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The first examples of Co( ii ) mesoionic carbene complexes (CoX 2 Dipp MIC 2 ; X = Cl − , Br − , I − ) demonstrate a new electronic perturbation on tetrahedral Co( ii ) complexes. Using absorption spectroscopy and magnetometry, the consequences of the MIC's strong σ-donating/minimal π-accepting nature are analyzed and shown to be further tunable by the nature of the coordinated halide.more » « less
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Cao, Wei; Mantanona, Alex J.; Mao, Haochuan; McCallum, Naneki C.; Jiao, Yang; Battistella, Claudia; Caponetti, Valeria; Zang, Nanzhi; Thompson, Matthew P.; Montalti, Marco; et al (, Chemistry of Materials)null (Ed.)
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